77290-89-2

Upstream product

• 15250-10-9 1-hydroperoxy-2-methylcyclohexanol 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 

Downstream Products

• 184001-45-4 2-methylhex-5-enoic acid [2-(3,4-dimethoxyphenyl)ethyl]amide 
• 107536-85-6 6-Allyl-6-methyl-cyclohex-2-enone 
• 184001-46-5 N-[2-(3,4-dimethoxyphenyl)ethyl]-N-(2-methylhex-5-enoyl)malonamic acid ethyl ester 
• 184001-38-5 2-diazo-N-<2-(3,4-dimethoxyphenyl)ethyl>-N-(2-methylhex-5-enoyl)malonamic acid ethyl ester 

Relevant academic research and scientific papers

Reactions of β-trimethylstannylcyclohexanones with peracids: Investigations into the stannyl-directed Baeyer-Villiger reaction

The trimethylstannyl subsituent raises the migratory aptitude of a primary β-carbon to be above that of a not otherwise activated secondary or tertiary carbon. This is apparent from the exclusive formation of the alkene acids 9-11 from Baeyer-Villiger reaction of the β-stannyl cyclohexanones 3-5. The stereoelectronic requirements of the stannyl-directed Baeyer-Villiger reaction were investigated using the axial β-trimethylstannlcyclohexanone 20.