77331-03-4Relevant articles and documents
Synthesis of α,α-Disulfenylated Aldehydes via Oxidative Transformation of Tertiary Amines
Huang, Xin,Wang, Jichao,Ni, Zhangqin,Wang, Sichang,Pan, Yuanjiang
, p. 5488 - 5491 (2015)
A method for the copper-catalyzed regioselective β-functionalization of tertiary amines with thiophenols has been developed. The control experiments and primary studies show that a thiyl radical is involved in the reaction, and the method provides a novel
Allylation with substituted vinylthionium ions from SnCl4 ionisation of 1,3- and 3,3-bis(alkyl/phenylthio)propenes
Hunter,Michael,Walter
, p. 9377 - 9398 (2007/10/02)
α- and γ-substituted vinylthionium ions from SnCl4 ionisation of a range of substituted 1,3- and 3,3-bis(alkyl/phenylthio)propenes allylate enol silyl ethers in good yield. Levels of regioselectivity are sterically dependent and in the case of
α-CETOALDEHYDES A GROUPEMENT ALDEHYDIQUE OU CETONIQUE PROTEGE
Duhamel, Lucette,Chauvin, Joe,Messier, Angela
, p. 4171 - 4174 (2007/10/02)
α-Ketoaldehydes with protected ketogroup 2 or protected aldehydrogroup 3 are obtained by reaction of thiophenol or methanol with α-chloro-α-(phenylthio)aldehydes 7.