77331-32-9

Basic information

• Product Name: 5-Isobutyl-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide
• Synonyms: 5-Isobutyl-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide
• CAS NO: 77331-32-9
• Molecular Weight: 451.374
• Mol File: 77331-32-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-Isobutyl-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Isobutyl-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide(77331-32-9)
• EPA Substance Registry System: 5-Isobutyl-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide(77331-32-9)

Safety Data

• Hazardous Substances Data: 77331-32-9(Hazardous Substances Data)

Upstream product

• 54211-56-2 3-methyl-1,4-diphenyl isothiosemicarbazide 
• 77331-28-3 3-methylthio-1,4-diphenyl-1,2,4-triazolium chloride 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 590-86-3 isovaleraldehyde 
• 503-74-2 3-methylbutyric acid 
• 74-93-1 methylthiol 
• 621-12-5 1,4-diphenylsemicarbazide 

Relevant articles and documents

THE CHAIN LENGTHENING OF ALIPHATIC ALDEHYDES WITH THE AID OF "NUCLEOPHILIC CARBENE"

The addition of "nucleophilic carbene" on 1,2,4-triazole bases (2) and aldehydes is decisively influenced by the anion present. 5-(α-Hydroxyalkyl)-1,2,4-triazolium chlorides, formed in the addition reaction of 3-methylthio-1,4-diphenyl-1,2,4-triazolium chloride (1c) with aldehydes, can be easily reduced to 5-alkyl-1,2,4-triazolium iodides (5).Reduction of these with NaBH4 affords aldehydes by acidic hydrolysis or carboxylic acids by alkaline hydrolysis, the carbon chain of which has been lengthened by one CH2 group, as compared to the starting aldehyde.