77385-74-1Relevant academic research and scientific papers
Alkenyl bromides by brominative deoxygenation of ketones in one or two steps
Von Roman,Ruhdorfer,Knorr
, p. 985 - 992 (2007/10/02)
The conversion of ketones into alkenyl bromides is accomplished in one or two steps by 2,2,2-tribromo-2,2-dihydro-1,3,2-benzodioxaphosphole or by the dibromomethyl methyl ether prepared therefrom. Investigations of the scope and limitations provide some hints for the preparative planning and improvement.
Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: Experimental and computational evidence for the formation of stable α-arylvinyl cations both by direct means and spontaneous exothermic isomerization of unstable isomeric ions
Apeloig, Yitzhak,Franke, Wilfried,Rappoport, Zvi,Schwarz, Helmut,Stahl, Daniel
, p. 2770 - 2780 (2007/10/02)
The kinetic energy release T which accompanies the Br· loss from ionized (E)- and (Z)-β-bromostyrenes (5 and 6) in the gas phase is higher by 0.7 ± 0.03 kcal mol-1 than that from the molecular ion of α-bromostyrene (4). Together with both colli
