773889-84-2

Upstream product

• 138325-07-2 ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate 
• 6485-40-1 (R)-Carvone 
• 773889-93-3 tert-butyl 2-[(1S,5R)-1-hydroxy-5-isopropenyl-2-methyl-2-cyclohexenyl]acetate 

Downstream Products

• 1359761-49-1 (1R,5S)-3-(2-(triisopropylsilyloxy)ethyl)-2-methyl-5-(prop-1-en-2-yl)-1-(prop-2-ynyl)cyclohex-2-enol 
• 1359761-48-0 (S)-3-(2-triisopropylsilyloxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone 
• 1359761-50-4 triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane 
• 1359761-47-9 (1S,5R)-1-(2-triisopropylsilyloxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enol 
• 773889-88-6 (1R,3S,5S)-1-(2-hydroxyethyl)-5-tri-isopropylsilyloxy-2-methylenecyclohexan-1,3-diol 
• 773889-80-8 (6R,7S,8S,10S)-10-benzoyloxy-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 
• 773889-90-0 (6R,7S,8S,10S)-10-benzyloxy-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 

Relevant academic research and scientific papers

Total synthesis of (+)-cyperolone

The total synthesis of (+)-cyperolone, an eudesmane-derived sesquiterpenoid from Cyperus rotundus, is described. The de novo synthesis was accomplished via a 15 step sequence starting from (R)-(-)-carvone. The synthetic route features a platinum-catalyzed

Regioselective isomerisation of highly substituted 1- methylenecyclohexenepoxides to the corresponding allylic alcohols. Influence of the base and of the protecting groups

Highly substituted 1-methylenecyclohexenepoxides 3, useful building blocks for a projected synthesis of wailupemycin A (1), were synthesized from (R)-carvone in eight synthetic steps in 23-40% overall yield. The regioselectivity of the subsequent isomeris