138325-07-2

Basic information

• Product Name: ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate
• Synonyms: ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate
• CAS NO: 138325-07-2
• Molecular Weight: 238.327
• Mol File: 138325-07-2.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate(138325-07-2)
• EPA Substance Registry System: ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate(138325-07-2)

Safety Data

• Hazardous Substances Data: 138325-07-2(Hazardous Substances Data)

Upstream product

• 6485-40-1 (R)-Carvone 
• 141-78-6 ethyl acetate 

Downstream Products

• 1359761-49-1 (1R,5S)-3-(2-(triisopropylsilyloxy)ethyl)-2-methyl-5-(prop-1-en-2-yl)-1-(prop-2-ynyl)cyclohex-2-enol 
• 1359761-48-0 (S)-3-(2-triisopropylsilyloxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone 
• 1359761-50-4 triisopropyl(2-((3R,5S)-2-methyl-5-(prop-1-en-2-yl)-3-(prop-2-ynyl)-3-(triethylsilyloxy)cyclohex-1-enyl)ethoxy)silane 
• 773889-88-6 (1R,3S,5S)-1-(2-hydroxyethyl)-5-tri-isopropylsilyloxy-2-methylenecyclohexan-1,3-diol 
• 773889-80-8 (6R,7S,8S,10S)-10-benzoyloxy-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 
• 773889-90-0 (6R,7S,8S,10S)-10-benzyloxy-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 
• 773889-84-2 (1S,5R)-1-(2-hydroxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enol 
• 138325-11-8 (+)-(5S)-3-carbethoxymethyl-5-(1-methyllethenyl)-2-methyl-2-cyclohexen-1-one 

Relevant articles and documents

Total synthesis of (+)-cyperolone

The total synthesis of (+)-cyperolone, an eudesmane-derived sesquiterpenoid from Cyperus rotundus, is described. The de novo synthesis was accomplished via a 15 step sequence starting from (R)-(-)-carvone. The synthetic route features a platinum-catalyzed

Regioselective isomerisation of highly substituted 1- methylenecyclohexenepoxides to the corresponding allylic alcohols. Influence of the base and of the protecting groups

Highly substituted 1-methylenecyclohexenepoxides 3, useful building blocks for a projected synthesis of wailupemycin A (1), were synthesized from (R)-carvone in eight synthetic steps in 23-40% overall yield. The regioselectivity of the subsequent isomeris

Efficient addition of cerium(III) enolate of ethyl acetate to ketones: application to the synthesis of β-ethoxycarbonylmethyl α,β-unsaturated ketones

The cerium(III) enolate derived from ethyl acetate was shown to undergo facile addition with ketones.With conjugated enones, 1,2-addition products were formed exclusively.Oxidative 1,3-oxygen transportation of these products provides an efficient route to