773889-80-8

Upstream product

• 773889-93-3 tert-butyl 2-[(1S,5R)-1-hydroxy-5-isopropenyl-2-methyl-2-cyclohexenyl]acetate 
• 773889-85-3 (6S,7S,8S,10R)-7,8-epoxy-10-isopropenyl-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 
• 773889-81-9 (1S,2S,3S,5R)-2,3-epoxy-1-(2-hydroxyethyl)-5-isopropenyl-2-methylcyclohexan-1-ol 
• 773889-84-2 (1S,5R)-1-(2-hydroxyethyl)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enol 
• 138325-07-2 ethyl 2-((1S,5R)-1-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)acetate 
• 6485-40-1 (R)-Carvone 
• 65-85-0 benzoic acid 
• 773889-86-4 (6R,7S,8S,10R)-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecan-10-ol 

Downstream Products

• 773889-88-6 (1R,3S,5S)-1-(2-hydroxyethyl)-5-tri-isopropylsilyloxy-2-methylenecyclohexan-1,3-diol 
• 773889-90-0 (6R,7S,8S,10S)-10-benzyloxy-7,8-epoxy-2,2,7-trimethyl-1,3-dioxaspiro[5.5]undecane 

Relevant academic research and scientific papers

Regioselective isomerisation of highly substituted 1- methylenecyclohexenepoxides to the corresponding allylic alcohols. Influence of the base and of the protecting groups

Highly substituted 1-methylenecyclohexenepoxides 3, useful building blocks for a projected synthesis of wailupemycin A (1), were synthesized from (R)-carvone in eight synthetic steps in 23-40% overall yield. The regioselectivity of the subsequent isomeris