77406-92-9

Basic information

• Product Name: 2-methylene-3-(methoxymethyloxy) cyclohexanone
• Synonyms: 2-methylene-3-(methoxymethyloxy) cyclohexanone
• CAS NO: 77406-92-9
• Molecular Weight: 170.208
• Mol File: 77406-92-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methylene-3-(methoxymethyloxy) cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylene-3-(methoxymethyloxy) cyclohexanone(77406-92-9)
• EPA Substance Registry System: 2-methylene-3-(methoxymethyloxy) cyclohexanone(77406-92-9)

Safety Data

• Hazardous Substances Data: 77406-92-9(Hazardous Substances Data)

Upstream product

• 77406-98-5 2-(1-Ethoxy-ethoxy)-7-iodo-4-methoxymethoxy-3-methylene-heptanenitrile 
• 77406-96-3 7-Iodo-4-methoxymethoxy-3-methylene-2-trimethylsilanyloxy-heptanenitrile 
• 77406-97-4 2-Hydroxy-7-iodo-4-methoxymethoxy-3-methylene-heptanenitrile 
• 77406-94-1 2-Diethoxymethyl-6-iodo-hex-1-en-3-ol 
• 77406-95-2 6-Iodo-3-methoxymethoxy-2-methylene-hexanal 
• 77406-99-6 1-(1-Ethoxy-ethoxy)-3-methoxymethoxy-2-methylene-cyclohexanecarbonitrile 

Downstream Products

• 77407-00-2 2-(2-octenyl)-3-butylcyclohexanone 
• 77407-09-1 3-Oxo-2-(6-oxo-cyclohex-1-enylmethyl)-octanoic acid methyl ester 
• 77407-04-6 2-(6-oxo-cyclohex-1-enylmethyl)malonic acid dimethyl ester 
• 77407-03-5 2-((benzyl(methyl)amino)methyl)cyclohex-2-en-1-one 
• 77407-06-8 2-(2-Methoxymethoxy-6-oxo-cyclohexylmethyl)-3-oxo-butyric acid methyl ester 
• 77407-02-4 ((Z)-2-Oct-2-enyl)-cyclohex-2-enone 
• 25435-63-6 2-Pentyl-2-cyclohexen-1-one 
• 77407-08-0 3-(6-Oxo-cyclohex-1-enyl)-2-phenylsulfanyl-propionic acid ethyl ester 
• 77407-05-7 2-(2-Methoxymethoxy-6-oxo-cyclohexylmethyl)-3-oxo-octanoic acid methyl ester 

Relevant articles and documents

REGIOSPECIFIC CARBON-CARBON BOND FORMATION AT α AND β POSITIONS IN CYCLIC KETONES VIA DOUBLE MICHAEL ADDITION TO α-METHYLENE-β-ALKOXY CYCLIC KETONE

Very reactive 2-methylene-3-alkoxycyclohexanone was synthesized.The 1,4-conjugate addition of various nucleophiles to this enone gave only β'-alkylated 2-cyclohexenone with simultaneous elimination of the β-alkoxy group.The second 1,4-conjugate addition of other nucleophile to the resulting cyclohexenone leads to the α and β disubstituted ketones.