77444-20-3

Upstream product

• 13866-14-3 cis-1-benzoyl-2,3-diphenylaziridine 
• 588-59-0 stilbene 
• 102478-96-6 1,2-Diphenyl-2-benzoyloxyethylamine hydrochloride 
• 77444-03-2 Ethyl N-chloro-N-(2-chloro-1,2-diphenylethyl)carbamate 
• 77444-01-0 Methyl N-chloro-N-(2-chloro-1,2-diphenylethyl)carbamate 
• 343222-48-0 2-Chloro-1,2-diphenylethyl isocyanate 
• 13698-13-0 Ethyl N-(2-chloro-1,2-diphenylethyl)carbamate 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 77444-07-6 2-Chloro-1,2-diphenylethylamine hydrochloride 
• 98-88-4 benzoyl chloride 
• 77444-19-0 2-Chloro-1,2-diphenylethylamine 
• 77444-02-1 Methyl N-(2-chloro-1,2-diphenylethyl)carbamate 

Downstream Products

• 102478-96-6 1,2-Diphenyl-2-benzoyloxyethylamine hydrochloride 
• 66166-17-4 N-(2-Hydroxy-1,2-diphenylethyl)benzamide 

Relevant academic research and scientific papers

Bifunctional asymmetric catalysis with hydrogen chloride: Enantioselective ring opening of aziridines catalyzed by a phosphinothiourea

Ring opening of aziridines with hydrogen chloride to form β-chloroamine derivatives is catalyzed by a chiral phosphinothiourea derivative in high yields and with high enantioselectivities. On the basis of 31P NMR studies, activation of HCl appears to proceed via quantitative protonation of the catalyst to afford a phosphonium chloride complex. Georg Thieme Verlag Stuttgart.

REACTIVITY OF N,N-DICHLOROURETHANES. XI. ADDITION OF N,N-DICHLOROURETHANES TO trans-STILBENE

N,N-Dichlorourethanes add readily to trans-stilbene with the formation of alkyl N-chloro-N-(2-chloro-1,2-diphenylethyl)carbamates, which give alkyl N-(2-chloro-1,2-diphenylethyl)carbamates when treated with an aqueous solution of sodium sulfite or thiosul