77492-62-7

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 91-20-3 naphthalene 
• 612-62-4 2-Chloroquinoline 
• 5332-24-1 3-bromoquinoline 
• 611-35-8 4-chloroquinoline 
• 89937-06-4 quinoline trifluoroacetate 
• 144369-63-1 diphenylselenium bis(1-adamantanecarboxylate) 
• 86-98-6 4,7-dichloroquinoline 

Relevant academic research and scientific papers

Alkylation of Heteroaromatic Bases with Diphenylselenium Diacyloxylate

Heteroaromatic bases were alkylated with selenuranes, which were formed by the reaction of diphenylselenoxide and carboxylic anhydrides, under photoirradiation conditions.This reaction was presumed to proceed via a radical pathway accompanying decarboxylation.

Electrolytic Adamantylation by Reductive Coupling of Quinolinylhalides in the Presence of 1-Bromoadamantane

Electrochemically generated anion radicals of a number of halogen-substituted quinolines 1a-g dehalogenate in N,N-dimethylformamide to halogen anions and radicals, which may stabilize by hydrogen abstraction from the solvent.In the presence of 1-bromoadamantane the fragments of reductive dehalogenation may be used synthetically for indirect generation of 1-bromoadamantane-radicals, which react predominantly to cross-coupled 2- and 7-monoadamantylated dihydroquinoline- and quinoline-structures, independent of the original halogen position.If C-2 is blocked, adamantylation takes place in the carbocyclic ring.Product distribution and cyclic-voltammetric results are discussed in terms of mechanism.