77515-94-7

Basic information

• Product Name: N,N,3-trimethyl-5-oxo-5-phenylpentanamide
• Synonyms: N,N,3-trimethyl-5-oxo-5-phenylpentanamide
• CAS NO: 77515-94-7
• Molecular Weight: 233.31
• Mol File: 77515-94-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N,3-trimethyl-5-oxo-5-phenylpentanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,3-trimethyl-5-oxo-5-phenylpentanamide(77515-94-7)
• EPA Substance Registry System: N,N,3-trimethyl-5-oxo-5-phenylpentanamide(77515-94-7)

Safety Data

• Hazardous Substances Data: 77515-94-7(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 13505-39-0 3-hydroxy-1-phenyl-butan-1-one 
• 127-19-5 N,N-dimethyl acetamide 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 

Relevant articles and documents

Stereochemistry of the Michael Addition of N,N-Disubstituted Amide and Thioamide Enolates to α,β-Unsaturated Ketones

A systematic study of the regio- and diastereoselectivity of the kinetic Michael addition of amide and thioamide enolates to a series of α,β-unsaturated ketones has been carried out.Factors that influence the diastereo- and regiochemical outcome of the reaction include the substitution pattern of the enone and enolate, the enolate counterion, and the solvent.Numerous examples of high selectivity have been discovered.In a number of examples, either the syn or the anti addition products can be obtained by varying the nature of the solvent, donor atom, and/or counterion.These results have correlated in terms of a coherent transition-state model.