77534-70-4 Usage
Description
N-MORPHOLINIUM TRIFLUOROMETHANESULFONATE, also known as NMTS, is a white crystalline solid that is highly soluble in water and polar organic solvents. It is a chemical compound commonly used as a reagent in organic synthesis, known for its high reactivity and stability.
Uses
Used in Organic Synthesis:
N-MORPHOLINIUM TRIFLUOROMETHANESULFONATE is used as a reagent for its ability to transfer a methyl group under mild reaction conditions, making it a mild and selective methylating agent for alcohols and phenols.
Used in Pharmaceutical and Agrochemical Preparation:
N-MORPHOLINIUM TRIFLUOROMETHANESULFONATE is used as a reagent in the preparation of various pharmaceuticals and agrochemicals, contributing to the development of new and improved products in these industries.
Used in Specialty Chemicals Synthesis:
N-MORPHOLINIUM TRIFLUOROMETHANESULFONATE is used as a reagent in the synthesis of specialty chemicals, where its high reactivity and stability make it a valuable tool for creating unique and complex molecules.
Check Digit Verification of cas no
The CAS Registry Mumber 77534-70-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,5,3 and 4 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 77534-70:
(7*7)+(6*7)+(5*5)+(4*3)+(3*4)+(2*7)+(1*0)=154
154 % 10 = 4
So 77534-70-4 is a valid CAS Registry Number.
InChI:InChI=1/C4H9NO.CHF3O3S/c1-3-6-4-2-5-1;2-1(3,4)8(5,6)7/h5H,1-4H2;(H,5,6,7)
77534-70-4Relevant articles and documents
Triflamides and triflates of six-membered heterocyclic amines
Shainyan,Tolstikov,Zhinkin
, p. 1180 - 1182 (2003)
Reactions of secondary cyclic amines (piperidine, morpholine, thiomorpholine, 1λ6,4-thiazinane-1,1-dione) with trifluoromethanesulfonic anhydride or with N-phenyltriflimide both in the presence and in the absence of a base (Et3N) result in formation of corresponding triflamides and triflates of the initial amines. The triflates and triflamides can be distinguished by their 19F and 15N NMR spectra and the presence in the IR spectra of salts of absorption bands in the region 3270-3000 cm-1 lacking in the spectra of triflamides.