77666-97-8

Basic information

• Product Name: Nonanoic acid, 9-(.alpha.-D-mannopyranosyloxy)-, methyl ester
• Synonyms: Nonanoic acid, 9-(.alpha.-D-mannopyranosyloxy)-, methyl ester
• CAS NO: 77666-97-8
• Molecular Formula: C₁₆H₃₀O₈
• Molecular Weight: 350.4
• Mol File: 77666-97-8.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Nonanoic acid, 9-(.alpha.-D-mannopyranosyloxy)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Nonanoic acid, 9-(.alpha.-D-mannopyranosyloxy)-, methyl ester(77666-97-8)
• EPA Substance Registry System: Nonanoic acid, 9-(.alpha.-D-mannopyranosyloxy)-, methyl ester(77666-97-8)

Safety Data

• Hazardous Substances Data: 77666-97-8(Hazardous Substances Data)

Upstream product

• 34957-73-8 methyl 9-hydroxynonanoate 
• 109681-59-6 8-methoxycarbonyloctyl 4,6-O-benzylidene-α-D-mannopyranoside 
• 115946-08-2 8-Methoxycarbonyloct-1-yl trifluoromethanesulfonate 
• 4132-28-9 2,3,4,6-tetra-O-benzyl-D-mannopyranose 
• 109681-56-3 3,4,6-tri-O-acetyl-1,2-O-<1-(8-methylcarbonyloctyloxy)ethylidene>-β-D-mannopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl bromide 
• 13242-53-0 acetobromomannose 
• 162130-01-0 9-(benzoyloxy)nonanoic acid 
• 140434-48-6 benzoic acid 9-hydroxynon-1-yl ester 
• 76436-70-9 Methyl 9-benzoyloxynonanoate 
• 183901-63-5 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate 
• 627466-98-2 2,3,4,6-tetra-O-benzoyl-α,β-D-mannospyranose 
• 3937-56-2 1,9-Nonanediol 
• 228850-23-5 8-(methoxycarbonyl)octyl 2,3,4,6-tetra-O-benzoyl-α-D-mannipyranoside 

Downstream Products

• 82086-32-6 8-methoxycarbonyloctyl 4,6-O-cyclohexylidene-3-O-(2,4-di-O-benzoyl-3,6-dideoxy-α-D-arabino-hexopyranosyl)-2-O-(tetra-O-benzyl-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 82086-26-8 8-methoxycarbonyloctyl 3-O-benzoyl-4,6-O-cyclohexylidene-2-O-(tetra-O-benzyl-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 82086-27-9 8-methoxycarbonyloctyl 4,6-O-cyclohexylidene-2-O-(tetra-O-benzyl-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 82086-25-7 8-methoxycarbonyloctyl 3-O-benzoyl-4,6-O-cyclohexylidene-α-D-mannopyranoside 
• 106450-66-2 8-methoxycarbonyloctyl 4,6-O-benzylidene-2-O-benzyl-α-D-mannopyranoside 
• 110524-45-3 8-methoxycarbonyloctyl 3-O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 110524-46-4 8-methoxycarbonyloctyl 2-O-benzyl-4,6-O-benzylidene-3-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 162129-96-6 8-(Methoxycarbonyl)octyl 2,3,4-tri-O-acetyl-6-O-trityl-α-D-mannopyranoside 
• 228850-32-6 8-{carboxy-[2-(fluoresceinylthioureido)ethyl]amido}octyl α-D-mannopyranoside 
• 228850-27-9 N-[9-(α-D-mannopyranosyloxy)nonanoyloxy]succinimide 
• 228850-28-0 8-(methoxycarbonyl)octyl (2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-(1->3)-[(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl)-(1->6)]-α-D-mannopyranoside 
• 146194-68-5 9-(α-D-mannopyranosyloxy)nonanoic acid 
• 109681-59-6 8-methoxycarbonyloctyl 4,6-O-benzylidene-α-D-mannopyranoside 
• 162129-90-0 9-((3aS,4S,5aR,9aR,9bS)-2,8-Diphenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxin-4-yloxy)-nonanoic acid methyl ester 

Relevant articles and documents

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8-(Methoxycarbonyl)octyl 3,6-di-O-(α-D-mannopyranosyl)-α-D-mannopyranoside (10) was synthesized in 54% yield by regioselective diglycosylation of unprotected mannoside 4, employing the trichloroacetimidate donor 1, followed by debenzoylation. Derivatives

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Glycosylation of suitably protected 8-methoxycarbonyloctyl alpha-D-manno-pyranosides with 2-O-acetyl-3,4,6-tri-O-benzyl-alpha-D-mannopyranosyl chloride provided alpha-D-Manp-(1----2)-alpha-D-Man, alpha-D-Manp-(1----3)-alpha-D-Man and alpha-D-Manp-(1----6)

PREPARATION OF 8-METHOXYCARBONYLOCTYL GLYCOSIDES OF α-D-MANNOPYRANOSE, 2-O-α-MANNOPYRANOSYL-α-D-MANNOPYRANOSE, β-D-GALACTOFURANOSE, AND 3-O-β-D-GALACTOFURANOSYL-α-D-MANNOPYRANOSE

The 8-methoxycarbonyloctyl glycosides of α-D-mannopyranose, 2-O-α-mannopyranosyl-α-D-mannopyranose, β-D-galactofuranose, and 3-O-β-D-galactofuranosyl-α-D-mannopyranose were prepared as intermadiates for the synthesis of complexes with the general structure mono-(or di-)saccharide-lipid spacer-protein having possible antigenic and immunogenic activity in respect to infection with Trypanosoma cruzi.Tri-O-acetyl-1,2-O-(1-methoxyethylidine) derivatives of D-mannopyranose and D-galactofuranose were teated with alcohols in the presence and absence of mercuric bromide to give othoesters which rearranged into glycosides.

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