109681-59-6Relevant articles and documents
SYNTHESIS OF IMMUNOSUPPRESIVE NEOGLYCOPROTEINS: BOVINE SERUM ALBUMIN COUPLED WITH 8-(HYDRAZINOCARBONYL)OCTYL 4- OR 6-O-&α-D-MANNOPYRANOSYL-&α-D-MANNOPYRANOSIDE
Wada, Kaoru,Chiba, Taku,Takei, Yutaka,Ishihara, Hideko,Hayashi, Hidetoshi,Onozaki, Kikuo
, p. 941 - 966 (2007/10/02)
Recombinant cytokines generated by bacteria, especially E.coli, are nonglycosylated.To investigate the effects of carbohydrates on their activities, we attempted to develop new cytokines by introduction of carbohydrates.As a model we synthesized neoglycop
PREPARATION OF 8-METHOXYCARBONYLOCTYL GLYCOSIDES OF α-D-MANNOPYRANOSE, 2-O-α-MANNOPYRANOSYL-α-D-MANNOPYRANOSE, β-D-GALACTOFURANOSE, AND 3-O-β-D-GALACTOFURANOSYL-α-D-MANNOPYRANOSE
Tsui, David S.,Gorin, Philip A. J.
, p. 1 - 8 (2007/10/02)
The 8-methoxycarbonyloctyl glycosides of α-D-mannopyranose, 2-O-α-mannopyranosyl-α-D-mannopyranose, β-D-galactofuranose, and 3-O-β-D-galactofuranosyl-α-D-mannopyranose were prepared as intermadiates for the synthesis of complexes with the general structure mono-(or di-)saccharide-lipid spacer-protein having possible antigenic and immunogenic activity in respect to infection with Trypanosoma cruzi.Tri-O-acetyl-1,2-O-(1-methoxyethylidine) derivatives of D-mannopyranose and D-galactofuranose were teated with alcohols in the presence and absence of mercuric bromide to give othoesters which rearranged into glycosides.