77708-65-7

Upstream product

• 126-81-8 dimedone 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 849595-89-7 3-(butyltellanyl)-5,5-dimethyl-cyclohex-2-enone 
• 1383373-17-8 5,5-dimethyl-3-[(1Z)-prop-1-en-1-yl]cyclohex-2-en-1-one 
• 100056-76-6 5,5-dimethyl-3-[(1E)-prop-1-en-1-yl]cyclohex-2-en-1-one 
• 1312797-55-9 5,5-dimethyl-3-(o-tolylethynyl)cyclohex-2-enone 
• 1312797-56-0 3-((2-methoxyphenyl)ethynyl)-5,5 dimethylcyclohex-2-enone 
• 29339-44-4 4'-methoxy-5,5-dimethyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one 
• 872452-01-2 3-(1-butoxyvinyl)-5,5-dimethylcyclohex-2-enone 
• 767-12-4 3,3-dimethylcyclohexanol 

Relevant academic research and scientific papers

Synthesis of 2-Arylpyridopyrimidinones, 6-Aryluracils, and Tri- and Tetrasubstituted Conjugated Alkenes via Pd-Catalyzed Enolic C-O Bond Activation-Arylation

A new and efficient approach for the synthesis of biologically important 2-aryl-4H-pyrido[1,2-a]pyrimidin-4-ones and 6-aryluracils via previously unknown Pd-catalyzed enolic C-OH activation-arylation of pyridopyrimidin-2,4-diones and barbituric acids, res

ANTICONVULSANT COMPOUNDS

The present application relates to compounds and methods for reducing the severity of convulsant activity or epileptic seizures, or for the treatment of chronic or acute pain.

First examples of a tosylate in the palladium-catalyzed Heck cross coupling reaction

The palladium-catalyzed cross coupling Heck reaction of tosylate (2) and methyl acrylate has been developed as an efficient method for carbon-carbon bond formation. The tosylate (2) was reacted with methyl acrylate using palladium acetate as catalyst to p

Facile Deoxygenation of Phenols and Enols Using Sodium Borohydride-Nickel Chloride

A facile deoxygenation reaction of phenol and 1,3-dicarbonyl compounds was investigated.Phenols, enolizable 1,3-diketones and 3-ketoesters were converted into the toluene-p-sulfonates which were reduced by a sodium borohydride-nickel chloride system to give the deoxygenated aromatic compounds, alcohols and esters, respectively.

Photochemical Reactivity of α-Sulfonyloxy Enones: An Easy Method for Arylation of 1,2-Diketones

3-Aryl-1,2-cyclohexanediones 4 are prepared conveniently by photolysis of the corresponding 2-((arylsulfonyl)oxy)cyclohex-2-enones 1.The reaction was shown to occur from a triplet excited state.A biphotonic process involving the normal photo-Fries product 14 as an intermediate was ruled out by preparing and irradiating this compound.The difference of reactivity between 1 and 2-((arylsulfonyl)amido)cyclohexenones is discussed.

Reversible Cyclization of N-(3-Hydroxy-1-Alkenyl)Pyridinium Salts to Pyridooxazines

Partially hydrogenated pyridooxazine, cyclopentapyridooxazine and pyridobenzoxazine ring systems were easily formed in the reaction of 3-hydroxy-2-(2-hydroxy-1,3-dioxo-2-indanyl)-2-alken-1-one derivatives with tosyl chloride and pyridine bases.A facile interconversion between pyridooxazines and the corresponding pyridinium salts was also realized.