849595-89-7

Upstream product

• 109-72-8 n-butyllithium 
• 77708-65-7 5,5-dimethyl-3-oxocyclohex-1-en-1-yl 4-methylbenzenesulfonate 
• 126-81-8 dimedone 
• 80534-76-5 diethyl 5,5-dimethyl-3-oxocyclohex-1-enyl phosphate 

Downstream Products

• 56745-22-3 3-butyl-5,5-dimethylcyclohex-2-en-1-one 
• 36047-17-3 5,5-dimethyl-3-phenyl-2-cyclohexen-1-one 
• 28017-78-9 3-Aethyl-5,5-dimethyl-2-cyclohexen-1-on 
• 29339-44-4 4'-methoxy-5,5-dimethyl-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one 
• 28017-80-3 3-tert-butyl-5,5-dimethylcyclohex-2-en-1-one 

Relevant academic research and scientific papers

Chemoselective reduction of β-butyltellanyl α,β-unsaturated carbonyl compounds to allylic alcohols

(Z)-β-Butyltellanyl α,β-unsaturated carbonyl compounds were stereoselectively produced by hydrotelluration of alkynones or by an addition/elimination sequence from enol tosylates. The β-butyltellanyl- enones were chemoselectively reduced with NaBH4/

Diastereoselective synthesis of α,β-unsaturated systems

Functionalized Z-vinylic tellurides were used in substitution reactions with lower order cyanocuprates leading to α,β-unsaturated ketones and esters in good yields. In the case of acyclic tellurides, the product was obtained in high diastereoselectivity. The control of the stereoselectivity was achieved by simple change of the reaction temperature.