777087-96-4Relevant articles and documents
Asymmetric Diels-Alder reaction of aminodienes with a nonracemic acrylate bound to rink resin: A comparison of these reactions with their solution-state analogues
Songis, Olivier,Geant, Pierre Yves,Sautrey, Guillaume,Martinez, Jean,Calmes, Monique
, p. 308 - 318 (2008/09/18)
The asymmetric Diels-Alder reactions between (3R)-4,4-dimethyl-2- oxopyrrolidin-3-yl acrylate derivatives and three N-Z-protected 1-aminodienes have been investigated both in solution and on a solid support. Comparable results for each reaction were obser
(R)-(4-(Benzyloxycarbonylphenyl)-3-hydroxy-4,4-dimethyl-2-pyrrolidinone) acrylate derivative as a chiral dienophile for the synthesis of enantiopure 2-aminocyclohexane carboxylic acids
Calmes, Monique,Didierjean, Claude,Martinez, Jean,Songis, Olivier
, p. 2173 - 2178 (2007/10/03)
An asymmetric Diels-Alder reaction between the enantiopure (R)-benzyl-4-(3-acryloyloxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)-benzoate (R)-2 and the N-Z-aminodiene 3 proceeded with total endo diastereoselectivity and was facially controlled in favour of the (
(R)- or (S)-4-(3-hydroxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)benzoic acid as a new chiral auxiliary for solid phase asymmetric Diels-Alder reactions
Akkari, Rhalid,Calmes, Monique,Escale, Francoise,Iapichella, Julien,Rolland, Marc,Martinez, Jean
, p. 2515 - 2525 (2007/10/03)
The synthesis of enantiopure (R)- and (S)-4-(3-hydroxy-4,4-dimethyl-2- oxopyrrolidin-1-yl)benzoic acid is described and the corresponding supported chiral acrylate derivative has been used as a dienophile in solid phase asymmetric Diels-Alder reactions wi