7771-25-7Relevant academic research and scientific papers
Tobacco smoke chemistry. 2. Alkyl and alkenyl substituted guaiacols found in cigarette smoke condensate.
Arnarp,Bielawski,Dahlin,Dahlman,Enzell,Pettersson
, p. 44 - 50 (2007/10/02)
A series of alkyl and alkenyl substituted guaiacols, which comprise a group of biologically and organoleptically active compounds, have been synthesized. Mass spectra and GC retention times for these have been recorded and compared with those obtained for constituents of a weakly acidic fraction of smoke condensate derived from American blend type cigarettes. On the basis of these results, 25 guaiacols have been identified, 18 of which have not been detected in tobacco smoke condensate previously.
1,3-Halogen shift of 2-halogeno-4,5-dimethylphenols following oxidation with Fremy's salt
Jacobs, A. W. C. M.,Maat, L.
, p. 183 - 185 (2007/10/02)
Oxidation of 2-bromo-6-deuterio-4,5-dimethylphenol with Fremy's salt, followed by in situ reduction, yielded mainly 3-bromo-4,5-dimethylpyrocatechol, which affords evidence for a 1,3-bromine shift during the oxidation.The same treatment of 2-chloro-4,5-di
