777916-04-8Relevant academic research and scientific papers
Preparation of the conjugated polyene chains with the 1,4-dimethyl substitution
Jeon, Hye-Sun,Koo, Sangho
, p. 7023 - 7026 (2004)
Allylic sulfones undergo the conjugate addition to diethyl chloroisopropylidenemalonate, followed by intramolecular cyclopropanation. DBU-promoted ring opening and subsequent desulfonation reactions of the resulting adduct produce the conjugated polyene chains with the 1,4-dimethyl substitution.
