Tetrahedron Letters p. 7023 - 7026 (2004)
Update date:2022-07-30
Topics:
Jeon, Hye-Sun
Koo, Sangho
Allylic sulfones undergo the conjugate addition to diethyl chloroisopropylidenemalonate, followed by intramolecular cyclopropanation. DBU-promoted ring opening and subsequent desulfonation reactions of the resulting adduct produce the conjugated polyene chains with the 1,4-dimethyl substitution.
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Doi:10.1134/S1070363220050096
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