77815-25-9Relevant academic research and scientific papers
HIGHLY CHEMOSELECTIVE SYNTHESIS OF KETONES FROM CARBOXYLIC ACIDS AND GRIGNARD REAGENTS USING α-CHLOROENAMINES AS A CONDENSATION REAGENT
Fujisawa, Tamotsu,Mori, Toshiki,Higuchi, Kazunobu,Sato, Toshio
, p. 1791 - 1794 (2007/10/02)
α-Chloroenamines are found to be an effective condensation reagent of carboxylic acids and Grignard reagents under mild conditions to afford chemoselectively the corresponding ketones in high yields and in one-pot operation.
ENANTIOSELECTIVE ALDOL CONDENSATIONS VIA BORON ENOLATES. A STERIC MODEL FOR ASYMMETRIC INDUCTION.
Evans, D. A.,Taber, T. R.
, p. 4675 - 4678 (2007/10/02)
Chiral boron enolates have been shown to be effective in stereoregulated aldol condensations.A transition state model is proposed for chirality transfer.
