7782-53-8Relevant academic research and scientific papers
Assembly of three coordination polymers from glycolate ligands: Syntheses, crystal structures, and thermal properties
Lin, Xue Song,Sang, Ya Li,Sun, Wei Dong,Yang, Su Hua
, p. 503 - 509 (2013)
Three transition metal-organic polymers, [Cu(η 2 -O 2CCH2OH)(μ 2-O2CCH 2OH)(H2O)] n (1), [Cu(μ 2-O 2CCH2OH)2] n (2), and [Cd(μ 2-O2CCH2OH)2] n (3) constructed from the rigid glycolate (HO2CCH2OH) ligand have been isolated under hydro(solvo)thermal conditions and structurally characterized by single-crystal X-ray diffraction. Polymer 1 presents a one-dimensional zigzag chain, while polymer 2 has a two-dimensional sheet structure. Polymer 3 exhibits a similar sheet structure as 2; however, the coordination modes of the ligands in complexes 1 and 2 are different. The three-dimensional solid-state supramolecular structures of the three polymers involve intermolecular hydrogen bonds. The thermal properties of the polymers have also been investigated.
Copper(II) Complexes of Hydroxyacetic Acid
Udupa, M. R.,Ramachandra, G. K.
, p. 430 - 433 (2007/10/02)
Copper(II) glycolate complexes with chloro and nitrato as anionic ligands, ammonia, morpholine, pyridine and 1-10, phenanthroline as neutral ligands and potassium as cation have been synthesized.The complexes are characterized by thermogravimetric analysis, magnetic susceptibility, electronic infrared and epr spectral measurements.
