77822-24-3Relevant articles and documents
Sex attractant pheromone of the pecan nut casebearer (Lepidoptera: Pyralidae)
Millar, Jocelyn G.,Knudson, Allen E.,McElfresh, J. Steven,Gries, Regine,Gries, Gerhard,Davis, James H.
, p. 331 - 339 (1996)
A female-produced sex pheromone for the pecan nut casebearer, Acrobasis nuxvorella Neunzig, has been identified from pheromone gland extracts of calling female moths. The compound (9E,11Z)-hexadecadienal [(9E,11Z)-16:Ald] was identified by coupled GC-EAD
PROCESS FOR PREPARING (9e, 11z)-9,11-HEXADECADIENAL
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, (2019/11/11)
An efficient process for preparing (9E,11Z)-9,11-hexadecadienal of formula (4) is provided. The process includes at least steps of: conducting a nucleophilic substitution reaction between an (8E,10Z)-8,10-pentadecadienyl magnesium halide derived from an (8E,10Z)-1-halo-8,10-pentadecadiene of (1): and an orthoformate ester (2) to thereby prepare a (9E, 11Z)-1,1-dialkoxy-9, 11-hexadecadiene (3): and hydrolyzing the (9E, 11Z)-1,1-dialkoxy-9,11-hexadecadiene (3) to obtain (9E, 11Z)-9,11-hexadecadienal (4).
Synthesis of E-vinyl iodides via Pd-catalyzed hydrostannation of terminal alkynes
Darwish, Alla,Chong, J. Michael
, p. 654 - 658 (2012/01/06)
E-Vinyl iodides may be prepared via a one-pot reaction involving Pd-catalyzed hydrostannation of terminal alkynes followed by iodinolysis of the intermediate vinylstannane. The synthesis is tolerant of functional groups, such as alcohols and esters.
Synthesis of (9E,11Z)-hexadeca-9,11-dienal, sex pheromone of the pecan nut casebearer, Acrobasis nuxvorella (Neunzig)
Passaro, Linda C.,Webster, Francis X.
, p. 1187 - 1190 (2007/10/03)
The pecan nut casebearer, Acrobasis nuxvorella (Neunzig), is a significant pest of the pecan nut industry. Two alternative syntheses of (9E,11Z)-hexadeca-9,11-dienal, the sex pheromone of the pecan nut casebearer, are described. The key transformation in
Identification, syntheses, and characterization of the geometric isomers of 9,11-hexadecadienal from female pheromone glands of the sugar cane borer Diatraea saccharalis
Santangelo, Ellen M.,Coracini, Myrian,Witzgall, Peter,Correa, Arlene G.,Unelius, C. Rikard
, p. 909 - 915 (2007/10/03)
Chemical analysis of the pheromone glands of the sugar cane borer Diatraea saccharalis has shown the presence of the four geometric isomers of 9,11-hexadecadienal (1-4), in addition to hexadecanal and (Z)-hexadec-11-enal. We here report the syntheses and characterization of compounds 1-4, One starting material, 9-decen-1-ol, has been used to obtain all of them via divergent synthetic routes.