778595-97-4

Basic information

• Product Name: 1-mercapto-7-phenyl-meta-carborane anion
• Synonyms: 1-mercapto-7-phenyl-meta-carborane anion
• CAS NO: 778595-97-4
• Molecular Weight: 252.391
• Mol File: 778595-97-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-mercapto-7-phenyl-meta-carborane anion(CAS DataBase Reference)
• NIST Chemistry Reference: 1-mercapto-7-phenyl-meta-carborane anion(778595-97-4)
• EPA Substance Registry System: 1-mercapto-7-phenyl-meta-carborane anion(778595-97-4)

Safety Data

• Hazardous Substances Data: 778595-97-4(Hazardous Substances Data)

Upstream product

• 16351-47-6 1-phenyl-1,7-dicarba-closo-dodecaborane⁽¹²⁾ 
• 7704-34-9 sulfur 

Relevant articles and documents

Exo-π-bonding to an ortho-carborane hypercarbon atom: Systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H 10 (X = F, OH or NH2) and related anions

The structures of derivatives of phenyl-ortho-carborane bearing on the second cage hypercarbon atom a π-donor substituent (F, OH, O-, NH2, NH- and CH2-) were investigated by NMR, X-ray crystallography and computational studies. The molecular structures of these compounds, notably their cage C1-C2 distances and the orientations of their π-donor substituents (OH, NH2, NH - and CH2-) show remarkable and systematic variations with the degree of exo π-bonding, which varies as expected with the π-donor characteristics of the substituent.