7788-51-4Relevant academic research and scientific papers
Iodine-mediated 1,2-aryl migration of primary benzhydryl amines
Chang, Junbiao,Du, Yangxu,Hao, Wei,Hou, Jiao,Lu, Qing,Yu, Wenquan
, p. 16223 - 16226 (2021/09/22)
An iodine-mediated 1,2-aryl migration reaction of primary benzhydryl amines under transition metal-free conditions has been achieved. The crude imines generated by this rearrangement reaction can be directly transformed into various aromatic secondary ami
THE ACTIVATION OF IMINES TO NUCLEOPHILIC ATTACK BY GRIGNARD REAGENTS
Brook, Michael,Jahangir
, p. 893 - 898 (2007/10/02)
The reaction of trimethylsilyl trifluoromethylmethanesulfonate (trimethylsilyl triflate, TMSOTf) with imines leads to the formation of N-trimethylsilyliminium salts which react efficiently with soft nucleophiles to form secondary amines.
