77970-17-3

Basic information

• Product Name: 3-nitrocyclohex-2-ene-1-one
• Synonyms: 3-nitrocyclohex-2-ene-1-one
• CAS NO: 77970-17-3
• Molecular Weight: 141.126
• Mol File: 77970-17-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-nitrocyclohex-2-ene-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-nitrocyclohex-2-ene-1-one(77970-17-3)
• EPA Substance Registry System: 3-nitrocyclohex-2-ene-1-one(77970-17-3)

Safety Data

• Hazardous Substances Data: 77970-17-3(Hazardous Substances Data)

Upstream product

• 1004-58-6 1,4-dioxa-spiro[4.5]dec-6-ene 
• 1521-51-3 rac-3-bromocyclohexene 
• 41771-12-4 C₁₂H₁₂ClN₃O₂ 
• 67730-57-8 3-nitro-2-cyclohexen-1-ol 
• 103724-93-2 3-nitrocyclohex-2-en-1-one ethylene acetal 
• 6925-08-2 3-nitrocyclohexene 
• 2562-37-0 1-nitrocyclohexene 
• 58008-75-6 7-Oxa-bicyclo[4.1.0]heptan-2-one oxime 

Downstream Products

• 75717-39-4 3-(phenylsulfanyl)cyclohex-2-en-1-one 
• 23740-61-6 2-(phenylsulfanyl)-2-cyclohexanone 
• 22009-37-6 7-methyl-3,4-dihydro-2H-naphthalen-1-one 
• 51015-29-3 6-methyl-3,4-dihydronaphthalen-1(2H)-one 
• 22009-38-7 7-hydroxy-1-tetralone 
• 6836-19-7 7-Methoxy-1-tetralone 
• 5674-05-5 5-isobutylcyclohexanone 
• 4668-64-8 2-(2-methylpropyl)cyclohexanone 
• 84057-30-7 7,7-dimethyl-cis-bicyclo<4.2.0>octan-2-one 

Relevant articles and documents

3-NITROCYCLOALKENONES, SYNTHESIS AND USE AS REVERSE AFFINITY CYCLOALKYNONE EQUIVALENTS

A partical synthesis of 3-nitrocycloalkenones and their utilization as dienophiles in the Diels-Alder reaction are discribed.The results demonstrate a reverse affinity equivalency between these β-nitro-enones and "cycloalkynones".

An unprecedented method for the generation of tert -butylperoxy radical using DIB/TBHP protocol: Solvent effect and application on allylic oxidation

Figure presented Tert-Butylperoxy radical was generated with PhI(OAc) 2 and tBuOOH. Ester solvent was found to be critical and the protocol was applied in the allylic oxidation of various olefinic substrates, which gave the corresponding α,β-unsaturated enones in good yield and regioselectivity.

Dirhodium(II) caprolactamate: An exceptional catalyst for allylic oxidation

The oxidation of organic molecules represents a fundamentally important chemical process. Particularly important is allylic oxidation, whereby a single methylene unit is converted directly into a carbonyl group. In this communication, we report that dirhodium(II) caprolactamate [Rh2(cap)4] in combination with tert-butyl hydroperoxide (terminal oxidant) effectively catalyzes the allylic oxidation of a variety of olefins and enones. The reaction is completely selective, tolerant of air/moisture, and can be performed with as little as 0.1 mol % catalyst in minutes. A mechanistic proposal involving redox chain catalysis has been put forth, as well as evidence for the intermediacy of a higher valent dirhodium tert-butyl peroxy complex. Copyright