51015-29-3

Basic information

• Product Name: 6-METHYL-1-TETRALONE
• Synonyms: 3,4-dihydro-6-methyl-1(2h)-naphthalenon;3,4-dihydro-6-methyl-1(2H)-Naphthalenone;3,4-dihydro-6-methylnaphthalen-1(2H)-one;6-Methyl-1,2,3,4-tetrahydronaphthalene-1-one;6-Methyl-3,4-dihydronaphthalen-1(2H)-one;6-Methyl-3,4-dihydronaphthalen-1(2H);6-METHYL-1-TETRALONE
• CAS NO: 51015-29-3
• Molecular Formula: C₁₁H₁₂O
• Molecular Weight: 160.21
• EINECS: 256-913-1
• Product Categories: pharmacetical
• Mol File: 51015-29-3.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 284.7 °C at 760 mmHg
• Flash Point: 119.7 °C
• Appearance: /
• Density: 1.074 g/cm³
• Vapor Pressure: 0.00294mmHg at 25°C
• Refractive Index: 1.557
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 6-METHYL-1-TETRALONE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-METHYL-1-TETRALONE(51015-29-3)
• EPA Substance Registry System: 6-METHYL-1-TETRALONE(51015-29-3)

Safety Data

• Hazardous Substances Data: 51015-29-3(Hazardous Substances Data)

Usage

Uses

6-Methyl-1-tetralone is a useful reagent in Photocatalytic reactions.

Synthesis Reference(s)

Tetrahedron, 43, p. 1847, 1987 DOI: 10.1016/S0040-4020(01)81496-4

InChI:InChI=1/C11H12O/c1-8-5-6-10-9(7-8)3-2-4-11(10)12/h5-7H,2-4H2,1H3

Upstream product

• 22156-45-2 4-(m-tolyl)butanoic acid 
• 104175-16-8 1-Oxo-6-methyl-1,2,3,4,7,8-hexahydro-naphthalin 
• 344754-09-2 3,4,4a,5,8,8a-hexahydro-6-methyl-1(2H)-naphthalenone 
• 1680-51-9 6-methyl-1,2,3,4-tetrahydronaphthalene 
• 591-17-3 meta-bromotoluene 
• 29480-08-8 1-(4-methylphenyl)cyclobutan-1-ol 
• 585-74-0 3-Methylacetophenone 
• 13061-96-6 dihydroxy-methyl-borane 
• 144464-64-2 5-oxo-5,6,7,8-tetrahydronaphthalen-2-yl trifluoromethanesulfonate 
• 833-85-2 5-(4-methylphenyl)-5-oxopentanoic acid 
• 51114-94-4 (2-carboxyethyl)triphenylphosphonium bromide 
• 99865-05-1 4-(p-tolyl)but-3-enoic acid 
• 66361-67-9 6-bromo-3,4-dihydro-2H-naphthalen-1-one 
• 3470-53-9 6-amino-1-tetralone 

Downstream Products

• 1680-51-9 6-methyl-1,2,3,4-tetrahydronaphthalene 
• 24894-78-8 6-methylnaphthalen-1-ol 
• 29304-60-7 7-methyl-4-phenyl-1,2-dihydronaphthalene 
• 1213846-17-3 6-methyl-1,2,3,4-tetrahydronaphthalen-1-amine 
• 1448775-15-2 C₁₁H₁₄O₂ 
• 1612867-51-2 (2Z,4E)-4-[6′-methyl-3′,4′-dihydro-1′(2′H)-naphthalen-1′-ylidene]-3-methyl-2-butenoic acid 
• 29304-61-8 6-methyl-1-phenylnaphthalene 

Relevant articles and documents

Intramolecular Cycloaddition Reactions of Conjugated Enynes

The intramolecular cycloaddition of conjugated enynes provides an efficient and general route to aromatic and dihydroaromatic compounds.

Synthesis of Novel Pterocarpen Analogues via [3?+?2] Coupling-Elimination Cascade of α,α-Dicyanoolefins with Quinone Monoimines

By employing triethylamine as a catalyst, [3?+?2] coupling-elimination cascade of α,α-dicyanoolefins with quinone monoimines was realized. The reactions afforded various novel pterocarpen analogues with generally moderate yields (up to 75%). In addition, a plausible reaction mechanism was proposed.

Intramolecular Büchner reaction and oxidative aromatization with SeO2 or O2

Intramolecular Büchner reaction of 1-diazo-5-phenylpentan-2-ones followed by oxidation with SeO2 or O2 in the presence of silica gel regioselectively gave 8-formyl-1-tetralones or one-carbon-lacking 1-tetralones, respectively.