78086-89-2Relevant academic research and scientific papers
RING-FORMING REACTION VIA REGIOSELECTIVE INTRAMOLECULAR INSERTION BY (PHENYLTHIO)CARBENE INTO α C-H BOND OF ALKOXIDES
Harada, Toshiro,Akiba, Eiji,Tsujimoto, Kohji,Oku, Akira
, p. 4483 - 4486 (1985)
ω-(Phenylthio)-ω-chloroalkyl acetates were allowed to react with MeLi (3.2 equiv) to give 2-(phenylthio)cycloalkanols which were produced by the regioselective intramolecular insertion by (phenylthio)carbenes.
Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion
Ritter, Robert H.,Cohen, Theodore
, p. 3718 - 3725 (2007/10/02)
Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri
Thiol-Oxygen Cooxidation Reactions of Cyclopentene, cis- and trans-But-2-ene, Norbornene, and Norbornadiene
Beckwith, Athelstan L. J.,Wagner, Rudolf D.
, p. 3638 - 3645 (2007/10/02)
Thiol-oxygen cooxidation (TOCO) of olefins, followed by reduction of the initially formed hydroperoxides with triphenylphosphine, affords β-hydroxy sulfides in moderate to good yields.The structures of the major products from cis- and trans-but-2-ene and
