RING-FORMING REACTION VIA REGIOSELECTIVE INTRAMOLECULAR INSERTION BY (PHENYLTHIO)CARBENE INTO α C-H BOND OF ALKOXIDES

DOI: 10.1016/S0040-4039(00)88936-4

Source and publish data:

Tetrahedron Letters p. 4483 - 4486 (1985)

Update date:2022-08-03

Topics:

Authors:

Harada, Toshiro

Akiba, Eiji

Tsujimoto, Kohji

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)88936-4

ω-(Phenylthio)-ω-chloroalkyl acetates were allowed to react with MeLi (3.2 equiv) to give 2-(phenylthio)cycloalkanols which were produced by the regioselective intramolecular insertion by (phenylthio)carbenes.

Full text of DOI:10.1016/S0040-4039(00)88936-4

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