83711-12-0

Basic information

• Product Name: 5,5-bis(phenylthio)-1-pentanol
• Synonyms: 5,5-bis(phenylthio)-1-pentanol
• CAS NO: 83711-12-0
• Molecular Weight: 304.477
• Mol File: 83711-12-0.mol

Chemical Properties

• CAS DataBase Reference: 5,5-bis(phenylthio)-1-pentanol(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-bis(phenylthio)-1-pentanol(83711-12-0)
• EPA Substance Registry System: 5,5-bis(phenylthio)-1-pentanol(83711-12-0)

Safety Data

• Hazardous Substances Data: 83711-12-0(Hazardous Substances Data)

Upstream product

• 1191-99-7 2,3-dihydro-2H-furan 
• 108-98-5 thiophenol 
• 109-99-9 tetrahydrofuran 
• 13307-76-1 [bis(phenylthio)methyl]lithium 
• 1927-61-3 2-(2-phenylethoxy)tetrahydro-2H-pyran 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 83711-10-8 1,1-bis(phenylthio)-6,6-bis-((p-tertbutylphenyl)thio)hexane 
• 83711-20-0 5-iodo-1,1-bis(phenylthio)pentane 
• 83711-04-0 6,6-bis(phenylthio)bicyclo<3.1.0>hexane 
• 263565-64-6 5,5-bis(phenylthio)pentyl 3-phenylpropanoate 
• 263565-65-7 5,5-bis(phenylthio)pentyl octanoate 
• 263565-59-9 5,5-bis(phenylthio)pentyl benzoate 
• 83711-13-1 5,5-bis(phenylthio)-1-pentyl benzenesulfonate 
• 65756-04-9 trans-(±)-2-(phenylthio)cyclopentanol 
• 78086-89-2 cis-2-(Phenylthio)cyclopentanol 

Relevant articles and documents

Ring Opening Alkylation of Tetrahydrofuran with Some Heterosubstituted Organolithium Reagents by the Aid of Boron Trifluoride Etherate

Organolithium reagents stabilized by halogeno, thio, silyl, vinyl and/or phenyl substituent(s) can cleave THF effectively under the influence of boron trifluoride etherate at lower temperatures.The softness of these carbanionic reagents seems to be import

Titanocene(II)-promoted olefination of ω,ω-bis(phenylthio)alkyl alkanoates. A new method for the preparation of ω-hydroxy ketones

Intramolecular olefination of esters having a thioacetal moiety was studied. The treatment of ω,ω-bis(phenylthio)alkyl alkanoates with Cp2Ti[P(OEt)3]2 and the following hydrolysis gave ω-hydroxy ketones in good yields. (C) 2000 Elsevier Science Ltd.

Catalyst-dependent selective synthesis of O/S- and S/S-acetals from enol ethers

Enol ethers are reacted with mercaptanes to give the corresponding O/S- or S/S-acetals in medium to high yield. Either product can be formed selectively depending on the acid catalyst and the reaction time applied.

Carbenoid Anion Behavior of Dilithio Derivatives of Thioacetal Alcohols. Stereochemistry and Mechanism of Ring Closures by Oxyanion-Facilitated CH Bond Insertion

Like other lithio derivatives of thioacetals bearing a second anionic site, dilithio derivatives of 3,3-, 5,5-, and 6,6-bis(phenylthio) alcohols decompose at or below ambient temperature to yield products ascribable to carbenoid intermediates.The 5,5-deri

MONOTHIOACETALIZATION OF ACETALS USING DIETHYLALUMINIUM THIOPHENOXIDE

Reactions of diethylaluminium thiophenoxide (Et2AlSPh) with acetals of several types, in which acyclic, cyclic, and bicyclic ones are involved, were examined in comparison with the known reaction using thiophenol in the presence of Lewis acid and found to provide a new and efficient method for preparation of monothioacetals.