78102-64-4

Upstream product

• 1807-68-7 diazodimedone 
• 64-19-7 acetic acid 
• 78102-62-2 2-Chlor-2-hydroxy-5,5-dimethyl-1,3-cyclohexandion 
• 75-36-5 acetyl chloride 
• 70990-64-6 2,3-Dihydroxy-5,5-dimethyl-2-cyclohexen-1-on 

Downstream Products

• 78102-77-9 2-Acetoxy-6-hydroxy-4,4-dimethyl-2,5-cyclohexadien-1-on 
• 70990-64-6 2,3-Dihydroxy-5,5-dimethyl-2-cyclohexen-1-on 

Relevant academic research and scientific papers

1,2,3-Cyclohexanetrione/2,6-Dihydroxy-2,5-cyclohexadien-1-one Isomerization: A Facile Synthesis of 2,6-Dioxy-substituted 2,5-Cyclohexadien-1-ones

Hitherto unknown 1,2,3-cyclohexanetriones 5 masked as chlorohydrins 2 or as chlorohydrin esters 4 are easily rearranged yielding the corresponding 2,6-dihydroxy-2,5-cyclohexadien-1-ones 6 or their ester 8.

Five- and Six-Membered Ring Reductones from 2-Diazo-1,3-dicarbonyl Compounds. A Smoothful Alternative of the Classic Thermal Dediazotation

2-Acyloxy-2-chloro-1,3-dicarbonyl compounds 2, easily obtained from 2-diazo-1,3-dicarbonyl compounds 1 and tert-butyl hypochlorite in formic or acetic acid at room temperature or below are immediately reduced to the corresponding reductone esters 3 by sod