78135-53-2Relevant academic research and scientific papers
Enantioselective Synthesis of (R)-(+)-Pulvilloric Acid
Roedel, Thomas,Gerlach, Hans
, p. 213 - 216 (2007/10/03)
The fungal metabolite (R)-(+)-pulvilloric acid was synthesized for the first time.Reaction of the Grignard reagent of 5 with 2-pentyloxirane (S)-(-)-4 in the presence of 1,5-cyclooctadienecopper(I) chloride as the catalyst led to (S)-(+)-6.The ena
Depsidone Synthesis. Part 16. Benzophenone-Grisa-3',5'-diene-2',3-dione-depsidone Interconversion: a New Theory of Depsidone Biosynthesis
Sala, Tony,Sargent, Melvyn V.
, p. 855 - 869 (2007/10/02)
The synthesis of a number of grisa-3',5'-diene-2',3-diones by oxidative coupling of substituted 2,2'-dihydroxy-4-methoxybenzophenones is described.The rearrangement of these grisadienediones to depsidones under basic, acidic, and thermal conditions is des
