78176-20-2Relevant academic research and scientific papers
SIMULTANEOUS OCCURRENCE OF ELECTRON TRANSFER INITIATED RADICAL CAGE COLLAPSE AND CHAIN MECHANISMS IN THE REACTIONS OF DIARYLIODONIUM CATIONS WITH 2-NITROPROPANATE ANION
Singh, P. R.,Khanna, R. K.
, p. 5355 - 5358 (1982)
Simultaneous occurrence of free radical cage and chain mechanisms initiated by single electron transfer in the reactions of diaryliodonium cations with 2-nitropropanate anion has been established.
Metal-Free C-Arylation of Nitro Compounds with Diaryliodonium Salts
Dey, Chandan,Lindstedt, Erik,Olofsson, Berit
, p. 4554 - 4557 (2015/09/28)
An efficient, mild, and metal-free arylation of nitroalkanes with diaryliodonium salts has been developed, giving easy access to tertiary nitro compounds. The reaction proceeds in high yields without the need for excess reagents and can be extended to α-arylation of nitroesters. Nitroalkanes were selectively C-arylated in the presence of other easily arylated functional groups, such as phenols and aliphatic alcohols.
The Chemistry of Aryllead(IV) Tricarboxylates. The C-Arylation of Nitroalkanes and Nitronate Salts with Aryllead Triacetates
Kozyrod, Robert P.,Pinhey, John T.
, p. 713 - 721 (2007/10/02)
2-Nitropropane reacts with phenyllead triacetate in dimethyl sulfoxide to give 2-nitro-2-phenylpropane in good yield.This arylation of nitroalkanes has been examined with a variety of substrates and a number of aryllead triacetates, and in those cases where there was no steric hindrance the reaction was found to be quite general.Reactions of nitroethane and methyl nitroacetate, compounds with two α-hydrogens, were readily controlled to give either the mono- or di-arylated products.The corresponding nitronate salts were also examined and found to undergo the arylation reaction in similar yield but at a very much faster rate.
The Arylation of Nitroalkanes and Nitronate Salts with Aryllead Triacetates
Kozyrod, Robert P.,Pinhey, John T.
, p. 783 - 784 (2007/10/02)
Nitroalkanes and their nitronate salts undergo α-arylation in good yield when treated with an aryllead triacetate in dimethyl sulfoxide.
