78184-86-8Relevant academic research and scientific papers
Facile Conversion of 2,3,4,6-Tetra-O-benzyl-D-glucopyranose into 1,3,4,5-Tetra-O-benzyl-L-sorbopyranose
Casiraghi, Giovanni,Rassu, Gloria,Cornia, Mara,Nicotra, Francesco
, p. 1242 - 1243 (1989)
The bromomagnesium salts of certain alcohols and phenols in dichloromethane cleanly promote the title transformation; the reaction proceeds via formal hydride transfer from C-5 to the anomeric carbon of the glucopyranose precursor.
Magnesium-mediated Wittig reagent-promoted Stereoselective synthesis of L-Sorbopyranoses from D-Glucopyranoses
Ullah, Karim,Li, Ming,Zheng, Yubin,Song, Wangze
, (2021)
L-Sorbose is an important rare sugar that exists in some natural products and widely used in pharmaceutical and chemical industries. Herein, two simple and practical routes were developed using cheap magnesium (II) for the synthesis of 1,3,4,5-tetra-O-ben
Method for preparing L-sorbose from D-glucose
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Paragraph 0023-0030, (2021/04/26)
The invention belongs to the technical field of organic synthesis, and provides a method for preparing L-sorbose from D-glucose. The method comprises the following step that in an organic solvent, under the action of a di-n-butyl magnesium catalyst, 2, 3,
Hydroxymethyl-Branched Polyhydroxylated Indolizidines: Novel Selective α-Glucosidase Inhibitors
Boisson, Julien,Thomasset, Amélia,Racine, Emilie,Cividino, Pascale,Banchelin Sainte-Luce, Thomas,Poisson, Jean-Fran?ois,Behr, Jean-Bernard,Py, Sandrine
, p. 3662 - 3665 (2015/08/18)
α,α-Disubstituted piperidines and conformationally constrained polyhydroxylated indolizidines bearing a hydroxymethyl substituent in position 8a were synthesized from a readily available l-sorbose-derived ketonitrone. Diastereoselective vinylation under t
SYNTHESIS OF 2,3,4,6-TETRA-O-BENZYL-L-IDOPYRANOSE
Helleur, Robert,Rao, Vanga S.,Perlin, Arthur S.
, p. 83 - 90 (2007/10/02)
A synthesis of 2,3,4,6-tetra-O-benzyl-L-idopyranose (15) is described, based on L-sorbose as the starting material.By a succession of well known, high-yielding procedures, the ketose was converted into a 2:1 mixture of 1,3,4,5-tetra-O-benzyl-2-O-(tert-but
