Journal of the Chemical Society. Chemical communications p. 1242 - 1243 (1989)
Update date:2022-09-26
Topics:
Casiraghi, Giovanni
Rassu, Gloria
Cornia, Mara
Nicotra, Francesco
The bromomagnesium salts of certain alcohols and phenols in dichloromethane cleanly promote the title transformation; the reaction proceeds via formal hydride transfer from C-5 to the anomeric carbon of the glucopyranose precursor.
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