78395-71-8

Upstream product

• 56656-06-5 1-methyl-3-(methylthio)-2-phenyl-1H-indole 
• 1757-72-8 1-methyl-2-phenyl-1H-indole-3-carbaldehyde 
• 53603-63-7 1-methyl-2-phenyl-3-nitroso-1H-indole 
• 62367-64-0 1-(1-methyl-2-phenyl-1H-indol-3-yl)ethan-1-one 
• 78395-78-5 1-methyl-2-phenyl-3-hydroxymethylindole 
• 67335-29-9 bis(1-methyl-2-phenyl-1H-indol-3-yl)methane 
• 78395-75-2 3-(4-nitrophenyldiazenyl)-1-methyl-2-phenyl-1H-indole 
• 67335-20-0 3,3'-(phenylmethylene)bis(1-methyl-2-phenyl-1H-indole) 
• 3558-24-5 1-methyl-2-phenyl-1H-indole 
• 75-52-5 nitromethane 
• 65814-47-3 N-(2-Brom-4-methylphenyl)-N-methylbenzamid 
• 4677-04-7 3-(phenyldiazenyl)-2-phenyl-1H-indole 
• 17375-64-3 3-acetyl-2-phenylindole 
• 4677-05-8 3-(phenyldiazenyl)-1-methyl-2-phenyl-1H-indole 

Downstream Products

• 78395-73-0 1-methyl-2-phenyl-3,6-dinitroindole 
• 53603-63-7 1-methyl-2-phenyl-3-nitroso-1H-indole 
• 78395-79-6 1-methyl-3,4-dinitro-2-phenylindole 

Relevant academic research and scientific papers

Nitromethane as a reagent for the synthesis of 3-nitroindoles from 2-haloarylamine derivatives

A new approach to the synthesis of 3-nitroindoles using palladium-catalyzed arylation of nitromethane with N-(2-bromoaryl)imidates was developed. A convenient and rapid method for cyclization of ethyl N-(2-nitromethylaryl)acetimidates to 2-methyl-3-nitro-1H-indoles was proposed.

Fused bisindole derivative and preparation method thereof

The invention discloses a fused bisindole derivative and a preparation method thereof. The preparation method provided by the invention comprises the following steps: adding an indole compound, sodiumnitrite and potassium persulfate into a solvent for rea

Method for preparing nitroindole derivatives

The invention discloses a method for preparing nitroindole derivatives. The method comprises the following steps: dissolving indole derivatives, sodium nitrate and potassium persulfate in a solvent, and reacting at 60-100 DEG C to obtain the nitroindole d

Reactions of indoles with nitrogen dioxide and nitrous acid in an aprotic solvent

The reaction of 2-phenyl- and 1-methyl-2-phenylindole with nitrogen dioxide or with nitrous acid (NaNO2-CH3COOH) in benzene leads mainly to the formation of the isonitroso and 3-nitroso indole derivatives, respectively. When reacted

ELECTRON-TRANSFER REACTIONS: REACTIONS OF INDOLES WITH NITROSONIUM ION. APPLICATION OF THE MARCUS THEORY. CRYSTAL STRUCTURES OF 1-METHYL-3,4-, 3,5- AND 3,6-DINITRO-2-PHENYLINDOLES

A series of 1-methyl-2-phenyl-3-substituted indoles, when reacted with nitrosonium tetrafluoroborate, formed mainly 3-nitro, 3,4-dinitro and 3,6-dinitro derivatives.Although Marcus theory agrees with the feasibility of an electron transfer (ET) between th

Electrophilic ipso-Substitutions. Part 3. Reactions of 3-Substituted Indoles, 4-Substituted N,N-Dimethylanilines, and 1- and 3-Substituted Indolizines with Nitrous Acid

Reactions of 3-substituted indoles, N,N-dimethylanilines, and 1- and 3-substituted indolizines with nitrous acid yield products of ipso-substitutions, essentially the corresponding nitro-derivatives.An electron transfer process is proposed for the initial

Electrophilic ipso-Substitutions. Part 1. Reaction of 3-Substituted Indoles with Nitronium and Nitrosonium Ions

3-Substituted indoles react with nitronium and nitrosonium ions to yield 3-nitroindole.In both cases the reaction was interpreted as an electrophilic ipso-substitution.The reaction mechanism is interpreted by hypothesizing the formation of a ?-complex-like intermediate, wich is some cases is preceded by an electron-transfer process.An order for the leaving abilities of the different electrofugal groups is discussed.