78395-73-0Relevant academic research and scientific papers
ELECTRON-TRANSFER REACTIONS: REACTIONS OF INDOLES WITH NITROSONIUM ION. APPLICATION OF THE MARCUS THEORY. CRYSTAL STRUCTURES OF 1-METHYL-3,4-, 3,5- AND 3,6-DINITRO-2-PHENYLINDOLES
Eberson, Lennart,Giorgini, Elisabetta,Greci, Lucedio,Tosi, Giorgio,Rizzoli, Corrado,et al.
, p. 45 - 52 (2007/10/02)
A series of 1-methyl-2-phenyl-3-substituted indoles, when reacted with nitrosonium tetrafluoroborate, formed mainly 3-nitro, 3,4-dinitro and 3,6-dinitro derivatives.Although Marcus theory agrees with the feasibility of an electron transfer (ET) between th
Electrophilic ipso-Substitutions. Part 1. Reaction of 3-Substituted Indoles with Nitronium and Nitrosonium Ions
Colonna, Martino,Greci, Lucedio,Poloni, Marino
, p. 628 - 632 (2007/10/02)
3-Substituted indoles react with nitronium and nitrosonium ions to yield 3-nitroindole.In both cases the reaction was interpreted as an electrophilic ipso-substitution.The reaction mechanism is interpreted by hypothesizing the formation of a ?-complex-like intermediate, wich is some cases is preceded by an electron-transfer process.An order for the leaving abilities of the different electrofugal groups is discussed.
