78569-36-5

Basic information

• Product Name: (E)-N-(naphthalen-1-yl)-1-phenylmethanimine
• Synonyms: (E)-N-(naphthalen-1-yl)-1-phenylmethanimine
• CAS NO: 78569-36-5
• Molecular Weight: 231.297
• Mol File: 78569-36-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-N-(naphthalen-1-yl)-1-phenylmethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(naphthalen-1-yl)-1-phenylmethanimine(78569-36-5)
• EPA Substance Registry System: (E)-N-(naphthalen-1-yl)-1-phenylmethanimine(78569-36-5)

Safety Data

• Hazardous Substances Data: 78569-36-5(Hazardous Substances Data)

Upstream product

• 134-32-7 1-amino-naphthalene 
• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 72142-85-9 2-Phenyl-naphtho<1,2-d>thiazol 
• 6361-33-7 N-(1-naphthyl)benzylamine 
• 92825-04-2 2,4-diphenyl-1,4-dihydro-2H-naphtho<1,2-d><1,3>thiazine 
• 92825-03-1 2,4-diphenyl-4H-naphtho<1,2-d><1,3>thiazine 

Relevant articles and documents

New insight into the nature of electron delocalization: The driving forces for distorting the geometry of stilbene-like species

To understand the nature of electron delocalization while questioning the abnormally large torsional angle θ of N-phenylmethylene-3-pyridineamine (6), we greatly improved our new program for energy partitioning. Meanwhile, the crystal structures of N-phen

Aerobic Oxidative Homo- and Cross-Coupling of Amines Catalyzed by Phenazine Radical Cations

Phenazine radical cations (PhRCs) were used for the first time as efficient metal-free catalysts for the oxidative homo- and cross-coupling of a variety of different amines. A series of functional PhRCs were prepared, characterized with X-ray diffraction, and their radical character was investigated with DFT calculations. They were tested as catalysts under neat conditions with low oxygen pressure to prepare homo- and cross-coupled aliphatic and aromatic imines in high yields. Although all synthesized phenazines were catalytically active, the highest reaction rates and the best selectivity were achieved using the 5,10-dihydro-5,10-dimethylphenazine radical cation. By means of fluorescence, UV-vis and EPR spectroscopy, a mechanism of the oxidative amine coupling, catalyzed by PhRCs, is proposed.

Combination of Enabling Technologies to Improve and Describe the Stereoselectivity of Wolff-Staudinger Cascade Reaction

A new, single-mode bench-top resonator was evaluated for the microwave-assisted flow generation of primary ketenes by thermal decomposition of α-diazoketones at high temperature. A number of amides and β-lactams were obtained by ketene generation in situ and reaction with amines and imines, respectively, in good to excellent yields. The preferential formation of trans-configured β-lactams was observed during the [2+2] Staudinger cycloaddition of a range of ketenes with different imines under controlled reaction conditions. Some insights into the mechanism of this reaction at high temperature are reported, and a new web-based molecular viewer, which takes advantage from Augmented Reality (AR) technology, is also described for a faster interpretation of computed data.