78570-32-8Relevant articles and documents
Reactions of Ketones with Molybdenum Nitrosyl Complexes: X-Ray Crystal Structures of (NO)I>2O>, a Complex having a Bent Mo-O-Mo Bond, and of a Bicyclic Salt, 1/2(I3)1/2>
Adams, Harry,Bailey, Neil A.,Denti, Gianfranco,McCleverty, Jon A.,Smith, John M. A.,Wlodarczyk, Andrzej
, p. 348 - 350 (1981)
Reaction of (NO)I2> with refluxing acetone or diacetone alcohol led to C-C bond cleavage and formation, in low yield, of (NO)I>2(μ-O)> and the bicyclic cation + (isolated as the I- or mixed I-/I3- salt); the structures of the last two were determined crystallographically, the μ-oxo species having a slightly bent Mo-O-Mo bond.