78640-30-9

Upstream product

• 1132-21-4 3,5-dimethoxybenzoic acid 
• 74-88-4 methyl iodide 
• 64286-79-9 3,5-dimethoxy-1-methylcyclohexa-2,5-diene-1-carboxylic acid 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 181486-39-5 (S)-2-{1-[4-((S)-1-Methoxycarbonyl-2-phenyl-ethylcarbamoyl)-4-methyl-2,6-dioxo-cyclohexylidene]-ethylamino}-3-phenyl-propionic acid methyl ester 
• 181486-35-1 3-Acetoxy-1-methyl-5-oxo-cyclohex-3-enecarboxylic acid methyl ester 
• 181486-36-2 4-acetyl-3,5-dioxo-1-methylcyclohexane carboxylic acid methyl ester 
• 181486-37-3 4-acetyl-3,5-dioxo-1-methylcyclohexane carboxylic acid 
• 181486-34-0 3,5-dioxo-1-methylcyclohexane carboxylic acid methyl ester 

Relevant academic research and scientific papers

A new linker for primary amines applicable to combinatorial approaches

We describe a new linker molecule (ADCC-linker) for the attachment of primary amines to solid support. The linker is stable towards acidic conditions (eg. TFA) basic conditions (eg. piperidine, DBU) as well as towards uronium type coupling reagents. The amine can be quantitatively released from the support using a 2% hydrazine in DMF solution.

Organometallic Compounds in Organic Synthesis. Part 13. Stereoselectivity of Complexation of Cyclohexadiene Esters

Complexation of cyclohexadienes with Fe(CO)3 as the entering group are subject to classical steric hindrance by alkyl groups, but CO2R and related groups introduce a competing factor because they favour sterically the entering group, probably through an i