78655-66-0Relevant academic research and scientific papers
A convenient procedure for smooth palladium-catalyzed allylic alkylation by sodium dimethyl malonate and cyclopentadienide. A new synthesis of allylic substituted cyclopentadienes.
Fiaud,Malleron
, p. 4437 - 4440 (1980)
The use of the Pd(dba)1 1 dba stands for dibenzylideneacetone2/dpe catalytic system in allylic alkylation allows sodium dimethyl malonate to react with allylic acetates at room temperature. According to this procedure, a novel synthe
TO WHAT EXTENT IS A ?-ALLYLIC INTERMEDIATE INVOLVED IN SOME PALLADIUM-CATALYZED ALKYLATIONS ?
Fiaud, J. C.,Malleron, J. L.
, p. 1399 - 1402 (2007/10/02)
Comparison of polarimetric data in the asymmetric palladium-catalyzed addition of sodium dimethyl malonate on optically active and racemic 2-cyclohexenyl and carveyl acetates suggests that the reaction does not got- at least totally -through a symmetric ?-allylic cationic intermediate.
