A convenient procedure for smooth palladium-catalyzed allylic alkylation by sodium dimethyl malonate and cyclopentadienide. A new synthesis of allylic substituted cyclopentadienes.

DOI: 10.1016/S0040-4039(00)92193-2

Source and publish data:

Tetrahedron Letters p. 4437 - 4440 (1980)

Update date:2022-08-02

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Authors:

Fiaud Fiaud

Malleron

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Article abstract of DOI:10.1016/S0040-4039(00)92193-2

The use of the Pd(dba)¹ 1 dba stands for dibenzylideneacetone₂/dpe catalytic system in allylic alkylation allows sodium dimethyl malonate to react with allylic acetates at room temperature. According to this procedure, a novel synthe

Full text of DOI:10.1016/S0040-4039(00)92193-2

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Product name:2-((1S,5R)-5-Isopropenyl-2-methyl-cyclohex-2-enyl)-malonic acid dimethyl ester

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