78680-98-5Relevant academic research and scientific papers
Higher Order Dipolar Cycloaddition Reactions of Diazoazoles with Electron-Rich Dipolarophiles
Padwa, Albert,Kumagai, Tsutomu,Woolhouse, Anthony D.
, p. 2330 - 2336 (2007/10/02)
A study of the cycloaddition behavior of a series of diazoazoles with electron-rich dipolarophiles has been carried out. 3-Diazo-4-methyl-5-phenylpyrazole readily reacts with ynamines, enamines, and vinyl ethers to give 1,7-cycloadducts.The trisubstituted
EXTENDED DIPOLAR CYCLOADDITION REACTIONS OF 3-DIAZOPYRAZOLES WITH ELECTRON RICH OLEFINS
Padwa, Albert,Kumagai, Tsutomo
, p. 1199 - 1202 (2007/10/02)
3-Diazo-4-methyl-5-phenylpyrazole readily adds to electron rich olefins to give 1,7-cycloadducts.The mechanism of the reaction consists of an initial 1,3-dipolar cycloaddition followed by a subsequent rearrangement.
