78709-01-0Relevant academic research and scientific papers
PREPARATION AND SYNTHTETIC UTILITY OF CYCLOPROPYL PHENYL SULFIDES
Bumgardner, C. L.,Lever, J. R.,Purrington, S. T.
, p. 2379 - 2382 (2007/10/02)
Primary alkyl halides and epoxides react with 1-lithiocyclopropyl phenyl sulfide to give derivatives suitable for transformation to carbonyl compounds or for desulfurization.
The chemistry of small ring compounds. Part 43. Synthesis of 1-substituted cyclopropyl sulfides
Jorritsma, R.,Steinberg, H.,Boer, Th. J. de
, p. 184 - 194 (2007/10/02)
1-Hydroxy- and 1-halocyclopropyl sulfides can be conveniently prepared starting from cyclopropanone.Cyclopropyl sulfides with halogen or a dimethylsulfonium group in the α-position can be transformed into 1-substituted cyclopropyl sulfides with a variety of nucleophiles.This means that the usual difficulties encountered with nucleophilic substitution at three-membered rings - i.e. low rates and ring opening - are largely removed by the presence of an alkylthio group at the same ring carbon atom as the leaving group.
