78719-73-0

Upstream product

• 6627-55-0 2-bromo-p-cresol 
• 67-64-1 acetone 
• 14002-89-2 4,6-dimethyl-chromen-2-one 
• 917-64-6 methyl magnesium iodide 
• 1450-72-2 5-methyl-2-hydroxyacetophenone 
• 22717-57-3 methyl 6-hydroxy-m-toluate 
• 74-88-4 methyl iodide 

Downstream Products

• 94853-45-9 1-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-2-isopropenyl-4-methyl-benzene 
• 94853-33-5 2-[2-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-5-methyl-phenyl]-propan-2-ol 
• 94853-39-1 2-[2-((E)-7-Methoxy-3,7-dimethyl-oct-2-enyloxy)-5-methyl-phenyl]-propan-2-ol 
• 78719-75-2 2-(2-Acetoxy-5-methyl-phenyl)-2,4,4,6-tetramethyl-chroman 
• 174867-46-0 2-(1-hydroxy-1-methylethyl)-4-methylphenyl tert-butyldimethylsilylether 
• 64298-10-8 1-methoxy-4-methyl-2-(prop-1-en-2-yl)benzene 
• 78719-74-1 4-Methyl-2-(2,4,4,6-tetramethyl-chroman-2-yl)-phenol 
• 174867-64-2 (3,4-dichlorophenoxy)methyl 2-(1-hydroxy-1-methylethyl)-4-methylphenyl methyl phosphate 
• 4427-56-9 Isothymol 
• 65490-14-4 2-isopropenyl-4-methylphenol 

Relevant academic research and scientific papers

Rapid intramolecular and C-O cleavage reactions of a phosphate triester catalysed by a neighbouring hydroxyl group

Three consecutive reactions are observed when the phosphate triester 6 is hydrolysed. At pH 12 M. 12 is then hydrolysed by C-O cleavage to give the diester 11. In base, the first two reactions are complete almost instantaneously, and the final phosphorus-containing products are (3,4-dichlorophenoxy)methyl methyl phosphate diester, and the methyl phosphate dianion. These must come from C-O cleavage reactions of diester 14 and the rearranged benzylic triester 15, which rapidly eliminate phosphate ester leaving groups to give the same quinone methide.

Synthesis of Aromatic Monoterpenyl Geranyl Ethers as Possible Insect Juvenile Hormon Mimics

Substituted phenyl geranyl (IX-XV, XXIV-XXVIII) and 7-methoxygeranyl ethers (XVI-XXIII, XXVIII) have been synthesised as possible juvenile hormon (JH) mimics.Out of these ethers only XVII, XVIII and XXIII show low JH activity.

Isothymol: Synthesis and Biogenesis

Isothymol (I), the C10-analogue of elvirol (II), has been synthesized from 2-hydroxy-5-methylacetophenone, and synthetic (I) is shown to be identical with natural isothymol.A probable biogenesis of I has been suggested.