787632-40-0

Upstream product

• 544455-39-2 (2S,3R)-3-Acetylamino-2-hydroxy-4-(4-methoxy-phenoxy)-butyric acid ethyl ester 
• 544455-38-1 ethyl (2E)-4-(4-methoxyphenoxy)but-2-enoate 
• 824-94-2 p-methoxybenzyl chloride 
• 787632-48-8 (2S,3R)-3-Acetylamino-2-(4-methoxy-benzyloxy)-4-(4-methoxy-phenoxy)-butyric acid ethyl ester 

Downstream Products

• 787632-49-9 N-[(1R,2S,3R)-3-Hydroxy-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-heptadecyl]-acetamide 
• 787632-44-4 (4R,5S,6S)-5-(4-Methoxy-benzyloxy)-4-(4-methoxy-phenoxymethyl)-2-methyl-6-vinyl-5,6-dihydro-4H-[1,3]oxazine 
• 787632-42-2 (4R,5S,6R)-5-(4-Methoxy-benzyloxy)-4-(4-methoxy-phenoxymethyl)-2-methyl-6-vinyl-5,6-dihydro-4H-[1,3]oxazine 
• 787632-43-3 N-[(1R,2S,3R)-3-Hydroxy-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-pent-4-enyl]-acetamide 
• 787632-41-1 N-[(1R,2S,3S)-3-Hydroxy-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-pent-4-enyl]-acetamide 
• 787632-47-7 N-[(E)-(1R,2S,3R)-3-Hydroxy-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-heptadec-4-enyl]-acetamide 
• 787632-46-6 N-[(E)-(1R,2S,3S)-3-Hydroxy-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-heptadec-4-enyl]-acetamide 

Relevant academic research and scientific papers

Oxazine formation by MsCl/Et3N as a convenient tool for the stereochemical interconversion of the hydroxyl group in N-acetyl 1,3-aminoalcohols. Asymmetric synthesis of N-acetyl L-xylo- and L-arabino-phytosphingosines

Use of MsCl/Et3N was proven to provide a convenient synthetic tool for the stereochemical intercoversion of the hydroxyl group in N-acetyl 1,3-aminoalcohols. Thus, under these conditions, the alcohols 4 and 6 smoothly converted to the oxazines

A highly efficient and stereoselective synthesis of polyhydroxylated pyrrolidines via regioselective asymmetric aminohydroxylation (RAA) and intramolecular amidomercuration reactions

A new synthetic strategy, which allows a complete stereochemical control of all four chiral centers of two important polyhydroxylated pyrrolidines 8 and 9, is described. The corner-stone of the present strategy is a successful implementation of the regios