787632-48-8

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 544455-39-2 (2S,3R)-3-Acetylamino-2-hydroxy-4-(4-methoxy-phenoxy)-butyric acid ethyl ester 
• 544455-38-1 ethyl (2E)-4-(4-methoxyphenoxy)but-2-enoate 
• 37746-78-4 4-bromo-trans-crotonic acid ethyl ester 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 544455-41-6 N-allyl-N-[3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-propyl]-acetamide 
• 544455-57-4 Benzoic acid (2R,3R,4S,5R)-1-acetyl-3-(tert-butyl-diphenyl-silanyloxy)-5-hydroxy-2-(4-methoxy-phenoxymethyl)-piperidin-4-yl ester 
• 544455-55-2 Acetic acid (2R,3R,4R,5R)-5-acetoxy-1-acetyl-3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-phenoxymethyl)-piperidin-4-yl ester 
• 544455-40-5 N-[3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-propyl]-acetamide 
• 544455-56-3 1-[(3aR,6R,7R,7aS)-7-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-phenoxymethyl)-2,2-dioxo-tetrahydro-1,3-dioxa-2λ⁶-thia-5-aza-inden-5-yl]-ethanone 
• 544455-48-3 Benzoic acid (3R,4S,5S,6R)-1-acetyl-4-hydroxy-5-(4-methoxy-benzyloxy)-6-(4-methoxy-phenoxymethyl)-piperidin-3-yl ester 
• 544455-43-8 (E)-(4R,5R)-5-(Acetyl-allyl-amino)-4-(4-methoxy-benzyloxy)-6-(4-methoxy-phenoxy)-hex-2-enoic acid ethyl ester 
• 544455-47-2 1-[(3aS,6R,7S,7aR)-7-(4-Methoxy-benzyloxy)-6-(4-methoxy-phenoxymethyl)-2,2-dioxo-tetrahydro-1,3-dioxa-2λ⁶-thia-5-aza-inden-5-yl]-ethanone 
• 544455-52-9 1-[3-(tert-butyl-diphenyl-silanyloxy)-2-(4-methoxy-phenoxymethyl)-3,6-dihydro-2H-pyridin-1-yl]-ethanone 
• 544455-46-1 1-[(3aS,6R,7S,7aS)-7-(4-Methoxy-benzyloxy)-6-(4-methoxy-phenoxymethyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyridin-5-yl]-ethanone 
• 544455-45-0 1-[(2R,3S,4S,5S)-4,5-Dihydroxy-3-(4-methoxy-benzyloxy)-2-(4-methoxy-phenoxymethyl)-piperidin-1-yl]-ethanone 
• 544455-58-5 Benzoic acid (2R,3R,4S,5R)-1-acetyl-3,5-dihydroxy-2-(4-methoxy-phenoxymethyl)-piperidin-4-yl ester 
• 544455-42-7 N-allyl-N-[2-(4-methoxy-benzyloxy)-1-(4-methoxy-phenoxymethyl)-3-oxo-propyl]-acetamide 
• 544455-44-9 1-[(2R,3R)-3-(4-Methoxy-benzyloxy)-2-(4-methoxy-phenoxymethyl)-3,6-dihydro-2H-pyridin-1-yl]-ethanone 

Relevant academic research and scientific papers

Oxazine formation by MsCl/Et3N as a convenient tool for the stereochemical interconversion of the hydroxyl group in N-acetyl 1,3-aminoalcohols. Asymmetric synthesis of N-acetyl L-xylo- and L-arabino-phytosphingosines

Use of MsCl/Et3N was proven to provide a convenient synthetic tool for the stereochemical intercoversion of the hydroxyl group in N-acetyl 1,3-aminoalcohols. Thus, under these conditions, the alcohols 4 and 6 smoothly converted to the oxazines

Stereodivergent total asymmetric synthesis of polyhydroxylated pyrrolidines via tandem allylic epoxidation and intramolecular cyclization reactions

Epoxidation of the allylic alcohols 10 and 11 using the VO(acac) 2/t-BuOOH system followed by an intramolecular 5-exo cyclization of the resulting δ-epoxycarbamates 12, 13, 18, and 19 has been shown to provide a general and efficient solution f

A highly efficient and stereoselective synthesis of polyhydroxylated pyrrolidines via regioselective asymmetric aminohydroxylation (RAA) and intramolecular amidomercuration reactions

A new synthetic strategy, which allows a complete stereochemical control of all four chiral centers of two important polyhydroxylated pyrrolidines 8 and 9, is described. The corner-stone of the present strategy is a successful implementation of the regios

A general methodology for the asymmetric synthesis of 1-deoxyiminosugars

A general methodology for the stereoselective synthesis of 1-deoxymannojirimycin and its three other stereoisomers is described. The achiral olefin 6 was converted through the common olefin intermediate 12 to the target compounds in a highly stereocontrol