78780-60-6

Basic information

• Product Name: benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside
• CAS NO: 78780-60-6
• Molecular Weight: 448.516
• Mol File: 78780-60-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(78780-60-6)
• EPA Substance Registry System: benzyl 3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(78780-60-6)

Safety Data

• Hazardous Substances Data: 78780-60-6(Hazardous Substances Data)

Upstream product

• 58650-53-6 benzyl exo-2,3:4,6-di-O-benzylidene-α-D-mannopyranoside 
• 56341-65-2 Benzyl 4,6-O-benzylidene-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 

Downstream Products

• 78727-71-6 benzyl 3,4-di-O-benzyl-α-D-mannopyranoside 
• 86342-15-6 benzyl 2-O-allyl-3,4-di-O-benzyl-α-D-rhamnopyranoside 
• 86342-17-8 benzyl 3,4-di-O-benzyl-α-D-rhamnopyranoside 
• 86342-13-4 benzyl 2-O-allyl-3,4-di-O-benzyl-6-O-(p-toluenesulfonyl)-α-D-mannopyranoside 
• 86353-43-7 benzyl 2-O-allyl-3,4-di-O-benzyl-α-D-mannopyranoside 
• 86342-12-3 benzyl 2-O-allyl-3-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 

Relevant articles and documents

CHEMO-, STEREO- AND REGIOSELECTIVE HYDROGENOLYSIS OF CARBOHYDRATE BENZYLIDENE ACETALS. SYNTHESIS OF BENZYL ETHERS OF BENZYL α-D-, METHYL β-D-MANNOPYRANOSIDES AND BENZYL α-D-RHAMNOPYRANOSIDE BY RING CLEAVAGE OF BENZYLIDENE DERIVATIVES WITH THE LiAlH4-AlCl3

Treatment of benzyl α-(1) and methyl β-D-mannopyranoside (2) with α,α-dimethoxytoluene gave the exo and endo isomers (3,5 and 4,6) of the dibenzylidene derivatives of 1 and 2.Hydrogenolysis of the exo isomers (3 and 5) with a molar equivalent of AlH2Cl ga