78805-81-9

Upstream product

• 78805-80-8 2-benzyl-2-azabicyclo[2.2.1]hept-5-en-3-one 
• 75409-90-4 2-benzyl-3-oxo-2-azabicyclo<2.2.1>hept-6-exo-yl p-toluenesulfonate 
• 38318-60-4 2-benzyl-3-oxo-6-exo-hydroxy-2-azabicyclo<2.2.1>heptane 
• 542-92-7 cyclopenta-1,3-diene 
• 100-39-0 benzyl bromide 
• 49805-30-3 2-azabicyclo[2.2.1.]hept-5-en-3-one 

Downstream Products

• 91290-06-1 (1R,2R,4S,5S)-2-Benzyl-5-hydroxy-2-aza-bicyclo[2.2.1]heptan-3-one 
• 95936-42-8 (1R,4S,6S)-2-Benzyl-6,7-dibromo-2-aza-bicyclo[2.2.1]heptan-3-one 
• 136465-16-2 Acetic acid (1S,4R,6R)-2-benzyl-7-bromo-3-oxo-2-aza-bicyclo[2.2.1]hept-6-yl ester 
• 136465-17-3 (1R,4S,6S)-2-Benzyl-7-bromo-6-hydroxy-2-aza-bicyclo[2.2.1]heptan-3-one 
• 136465-19-5 2-benzyl-6-exo-fluoro-7-anti-bromo-2-azabicyclo<2.2.1>-heptan-3-one 
• 136465-20-8 (1R,4R,6R)-2-Benzyl-6-fluoro-2-aza-bicyclo[2.2.1]heptan-3-one 
• 91290-07-2 (1R,2R,4S)-2-Benzyl-2-aza-bicyclo[2.2.1]heptane-3,5-dione 

Relevant academic research and scientific papers

BIOHYDROXYLATION D'UN AZA-2 BICYCLO HEPTANE

Biohydroxylation with Beauveria sulfurescens of the 5-exo position of the 2-aza bicycloheptane ring system gives rise to a precursor of carbocyclic 2'-deoxy nucleosides.

Synthesis of Diphenyl Ether Models of Thyroid Hormones. Diphenyl Ethers Linked to the 3-Oxo-2-azabicycloheptane Ring System as Substrates for Conformational Analysis

A series of diphenyl ethers linked to 2-azabicyclooctan-3-ones and 2-azabicycloheptan-3-ones were synthesized as substrates for conformational analysis using the lanthanide shift reagent NMR technique.The materials were prepared by displacement of the exo-6-tosyloxy bicyclic lactam with the corresponding phenoxide which results in formation of the phenyl ether with retention of stereochemistry.This double-inversion process presumably involves anchimeric assistance by the lactam nitrogen.The synthesis and properties of a number of these systems are described.Complete 13C assignments for the series are presented.