78822-86-3

Basic information

• Product Name: (1S,2R,3S,4S)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol
• Synonyms: (1S,2R,3S,4S)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol
• CAS NO: 78822-86-3
• Molecular Weight: 318.437
• Mol File: 78822-86-3.mol

Chemical Properties

• CAS DataBase Reference: (1S,2R,3S,4S)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,3S,4S)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol(78822-86-3)
• EPA Substance Registry System: (1S,2R,3S,4S)-2-((R)-Benzenesulfinyl)-3-methyl-1-phenyl-pentane-1,4-diol(78822-86-3)

Safety Data

• Hazardous Substances Data: 78822-86-3(Hazardous Substances Data)

Upstream product

• 78837-34-0 (2S,3R)-3-Methyl-4-phenylsulfanyl-butan-2-ol 
• 100-52-7 benzaldehyde 
• 78822-84-1 (2R,3S)-4-((R)-Benzenesulfinyl)-3-methyl-butan-2-ol 
• 80125-63-9 (2S,3S)-4-((R)-Benzenesulfinyl)-3-methyl-butan-2-ol 
• 78822-84-1 (2S,3R)-4-((R)-Benzenesulfinyl)-3-methyl-butan-2-ol 
• 78822-84-1 1-<2(S)-methyl-3(S)-hydroxy>butylphenyl (R)-sulfoxide 
• 78837-34-0 (+/-)-threo-4-(Phenylthio)-3-methyl-2-butanol 
• 78822-85-2 C₁₁H₁₅LiO₂S 
• 100-68-5 methyl-phenyl-thioether 

Downstream Products

• 80091-13-0 (+/-)-(2S^*, 3S^*, 4S^*, 5R^*)-tetrahydro-2,3-dimethyl-5-phenyl-4-(phenylthio)furan 
• 78822-87-4 (1S,2R,3S,4R)-3-Methyl-1-phenyl-2-phenylsulfanyl-pentane-1,4-diol 
• 78822-87-4 (+/-)-(1R^*, 2S^*, 3S^*, 4S^*)-3-methyl-1-phenyl-2-(phenylthio)-1,4-pentanediol 
• 78822-88-5 (+/-)-(1R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-1,4-pentadienol 
• 80091-13-0 (+/-)-(2S^*, 3S^*, 4R^*, 5S^*)-tetrahydro-2,3-dimethyl-5-phenyl-4-(phenylthio)furan 
• 78822-87-4 (+/-)-(1S^*, 2R^*, 3S^*, 4S^*)-3-methyl-1-phenyl-2-(phenylthio)-1,4-pentanediol 
• 78822-88-5 (+/-)-(1S^*, 3S^*, 4S^*)-3-methyl-1-phenyl-1,4-pentadienol 
• 110891-04-8 Acetic acid (1S,2R,3S,4S)-4-acetoxy-2-((R)-benzenesulfinyl)-3-methyl-1-phenyl-pentyl ester 
• 78822-88-5 (+/-)-(1S^*, 3R^*, 4S^*)-3-methyl-1-phenyl-1,4-pentadienol 
• 80091-13-0 (+/-)-(2S^*, 3R^*, 4R^*, 5R^*)-tetrahydro-2,3-dimethyl-5-phenyl-4-(phenylthio)furan 
• 78822-87-4 (+/-)-(1R^*, 2R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-(phenylthio)-1,4-pentanediol 
• 80091-13-0 (+/-)-(2S^*, 3R^*, 4R^*, 5S^*)-tetrahydro-2,3-dimethyl-5-phenyl-4-(phenylthio)furan 
• 78822-87-4 (+/-)-(1S^*, 2R^*, 3R^*, 4S^*)-3-methyl-1-phenyl-2-(phenylthio)-1,4-pentanediol 
• 80091-13-0 (+/-)-(2S^*, 3R^*, 4S^*, 5S^*)-tetrahydro-2,3-dimethyl-5-phenyl-4-(phenylthio)furan 

Relevant articles and documents

STUDIES OF STEREOCHEMICAL CONTROL USING α-LITHIOSULFINYL CARBANIONS

The stereoselectivity in reactions of α-lithiosulfinyl carbanions with aldehydes has been unambiguously established.Steric effects and intramolecular chelation of the associated cation are important factors contributing to the observed outcome.

A Stereoselective Approach to Acyclic Systems via Condensations of α-Lithiosulfinyl Carbanions and Aldehydes

The stereochemical outcome of condensations of α-lithiosulfinyl carbanions with aldehydes is presented, and demonstrates useful methodology for generating 1,2-asymmetry, as well as construction of 1,3-asymmetric relationships in acyclic systems.